Difference between revisions of "Crosslinker"

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==Vernetzer als Additive==
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==Crosslinker as additive==
Die Bindemittel der [[Top Coat|Top Coats]] und [[Lederfarbe|Pigmentfarben]] sind i. d. R. auf Polyurethanbasis. '''"Vernetzer"''' oder englisch '''"Crosslinker"''' sind Additive, die in wässrigen Top Coats und Pigmentfarben auf Polyurethanbasis eingesetzt werden. Der Vernetzer "vernetzt" die Polyurethanbindemittel und sorgt dadurch für die notwendigen [[Echtheiten]] der [[Leder]]oberfläche. Durch die "Vernetzung" werden die Lederoberflächen [[Zurichtung|pigmentierter Leder]] resistenter gegen Abrieb, Feuchtigkeit oder Lösungsmittel.
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The binders of the [[finish#Primer - Finish / Top Coat|top coat]] and [[leather colour|pigment leather paint]] are generally based on polyurethane. "Crosslinkers" are additives which are used in aqueous top coats and pigment paint based on polyurethane. The crosslinker "crosslinks" the polyurethane binders and thereby ensures the necessary [[leather quality|fastness properties]] of the leather surface. By "cross-linking", the leather surfaces of [[finish|pigmented leather]] are more resistant to [[leather damages|abrasion, moisture or solvents]].
  
Insbesondere bei anspruchsvollen Oberflächen wie [[Autoleder|Autoledern]] haben sich Isocyanat-Vernetzer bewährt. Isocyanat-Vernetzer vergilben nicht und sind auch sonst sehr alterungsbeständig. Dazu sind Isocyanat-Vernetzer leicht anzuwenden und nach der Verarbeitung ungefährlich für die Gesundheit oder Umwelt.
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Isocyanate crosslinkers have proven particularly effective on demanding surfaces such as [[car leather|automotive leathers]]. Isocyanate crosslinkers do not turn yellow and are also very resistant to ageing. To this end, isocyanate crosslinkers are easy to use and are not harmful to health or the [[Environmental protection|environment]] after processing.
  
Bei [[Möbelleder|Möbelledern]] sind Aziridin-Vernetzer verbreitet.
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Aziridine crosslinkers are common in [[leather furniture|furniture leather]].
  
Vernetzer enthalten i. d. R. organische Lösungsmittel. Diese sind notwendig, um eine ausreichende Vermischung mit der zu vernetzenden Substanz zu erreichen. Die Hersteller versuchen diesen Lösungsmittelanteil zukünftig auf Null zu reduzieren.
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Crosslinkers generally contain organic solvents. These are necessary in order to achieve sufficient mixing with the substance to be cross-linked. The manufacturers of crosslinkers are trying to reduce this solvent proportion to zero.
  
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==Other top coat additives==
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In addition to the crosslinkers, there are many more additives for the top coat. Some additives change the [[haptic evaluation of leather surfaces]]. Additives can influence the grip of the leather. It can feel more waxy, rough or smooth.
  
==[[Haptik|Griffmittel]] als Additive==
 
Neben den Vernetzern gibt es aber noch eine weitere Anzahl von Additiven für den [[Top Coat]]. Dazu zählen auch die Griffmittel. Griffmittel verändern den "Griff" (die [[Haptik]]) des Leders. Über ein Griffmittel steuert man, ob sich ein Leder mehr wachsig, stumpf oder glatt anfühlt.
 
  
 
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==Spider's web effect by aziridine crosslinker==
==Spinn web effect by aziridine crosslinker==
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The first generations of aziridine-based crosslinkers resulted in the formation of the so-called spider's web effect. The phenomenon first appeared in the previous century. The crosslinker reacted with time and became so hard that the surface [[leather damages|broke years later]], causing a fracture pattern similar to that of a spider's web. [[car leather#Jaguar|Jaguar]] and other British brands were affected. Nowadays, this problem seldom.
Bei den ersten Generationen von Vernetzern auf Aziridin-Basis kam es bei der Anwendung bei der Lederzurichtung zum sogenannten Spinnwebe-Effekt. Bekannt ist das Phänomen aus dem vorherigen Jahrhundert. Der Vernetzer reagierte mit der Zeit nach und wurde so hart, dass die Oberfläche Jahre später brach und ein Spinnwebe ähnliches Bruchbild entstand. Jaguar und andere britische Marken waren davon betroffen. Heutzutage hat man dieses Problem im Griff.  
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[[bild:Aziridin-Vernetzer-01.jpg|250px]]
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[[bild:Aziridin-Vernetzer-01.jpg|500px]]
[[bild:Aziridin-Vernetzer-05.jpg|250px]]
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[[bild:Aziridin-Vernetzer-05.jpg|500px]]
 
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<p>&nbsp;</p>
 
<p>&nbsp;</p>
  
<werbebanner />
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[[bild:Hard-finish-crack-leather-02.jpg|500px]]
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</p>
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''Typical cracks in the [[finish]] of modern leather due to poor [[leather quality|finish quality]].''<br></p>
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<p>&nbsp;</p>
  
 
== Additional information ==
 
== Additional information ==

Latest revision as of 20:03, 16 January 2023

LEATHER-DICTIONARY.jpg


Crosslinker as additive

The binders of the top coat and pigment leather paint are generally based on polyurethane. "Crosslinkers" are additives which are used in aqueous top coats and pigment paint based on polyurethane. The crosslinker "crosslinks" the polyurethane binders and thereby ensures the necessary fastness properties of the leather surface. By "cross-linking", the leather surfaces of pigmented leather are more resistant to abrasion, moisture or solvents.

Isocyanate crosslinkers have proven particularly effective on demanding surfaces such as automotive leathers. Isocyanate crosslinkers do not turn yellow and are also very resistant to ageing. To this end, isocyanate crosslinkers are easy to use and are not harmful to health or the environment after processing.

Aziridine crosslinkers are common in furniture leather.

Crosslinkers generally contain organic solvents. These are necessary in order to achieve sufficient mixing with the substance to be cross-linked. The manufacturers of crosslinkers are trying to reduce this solvent proportion to zero.

Other top coat additives

In addition to the crosslinkers, there are many more additives for the top coat. Some additives change the haptic evaluation of leather surfaces. Additives can influence the grip of the leather. It can feel more waxy, rough or smooth.


Spider's web effect by aziridine crosslinker

The first generations of aziridine-based crosslinkers resulted in the formation of the so-called spider's web effect. The phenomenon first appeared in the previous century. The crosslinker reacted with time and became so hard that the surface broke years later, causing a fracture pattern similar to that of a spider's web. Jaguar and other British brands were affected. Nowadays, this problem seldom.


Aziridin-Vernetzer-02.jpg

Aziridin-Vernetzer-01.jpg

Aziridin-Vernetzer-05.jpg

Cracking of the surface due to excessive crosslinking of the aziridine crosslinker.

 

Hard-finish-crack-leather-02.jpg

Typical cracks in the finish of modern leather due to poor finish quality.

 

Additional information


Colourlock-GB-03.jpg

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